Watching that video I posted above got me thinking. Which episode/scene of Breaking Bad, upon watching it, got you thinking that this is a special television show? Which one made you sit up and take notice? For me, it was actually pretty early on. I got into the show much later than everyone else (series 4 had just aired) and I was hearing all sorts of brilliant things about it.
Naturally, I was a little sceptical whether it would live up to the hype but I was convinced it would when Walt killed Krazy-8 in the basement. That entire episode was brilliant. The fact that Walt was still a man with morals and was going to let him go. The way he drew up the 'pros and cons' list when debating whether to kill him (Just the one 'con': "He will kill your entire family"). And then the best scene of them all was when Walt realised there was a jagged edge of plate missing from the broken plate and deduced that Krazy-8 had it and intended to kill Walt. That was the scene that changed Walt in my eyes, and it set the tone for the rest of the series. Pretty special television and from then on I was hooked.