Apparently one of the comments notes no team ever has come close to xG of 5. Is that true? Fascinating if true.
There's different xG models out there but it happens. Found these just looking through Barcelona, Bayern, Liverpool, Man City and Real Madrid results since 14/15 (domestic league only).
A quick look at PSG's league results say they have hit 5+ xG too but I can't be bothered going through anymore/typing them out. Then there's all the leagues and competitions out there so safe to say it does indeed occur.
21/22 Bayern 6.88-1.23 Bochum (7-0)
19/20 Man City 6.83-0.34 Watford (8-0)
15/16 Barcelona 6.13-0.62 Gijon (6-0)
18/19 Barcelona 6.04-1.64 Huesca (8-2)
19/20 Bayern 5.84-0.54 Bremen (6-1)
15/16 Deportivo 2.20-5.76 Barcelona (0-8)
17/18 Man City 5.73-0.61 Palace (5-0)
15/16 Real Madrid 5.72-0.93 Rayo Vallecano (10-2)
17/18 Barcelona 5.55-0.75 Espanyol (5-0)
18/19 Bayern 5.36-0.87 Hannover (3-1)
14/15 Man City 5.35-0.87 QPR (6-0)
21/22 Liverpool 5.33-0.14 Leeds (6-0)
17/18 Real Madrid 5.31-0.98 Real Sociedad (5-1)
21/22 Hertha Berlin 0.85-5.19 Bayern (1-4)